Poly[[μ2-(1Z,N′E)-2-(1,3-benzothiazol-2-ylsulfanyl)-N′-(2-oxidobenzylidene-κ2 O:O)acetohydrazidato-κ2 O,N′](pyridine-κN)copper(II)]
نویسندگان
چکیده
In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone mol-ecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine mol-ecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu-O-Cu chains along [001]. Several weak π-π inter-actions between benzothia-zole rings were found in the same direction [centroid-centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å].
منابع مشابه
Poly[bis(μ2-formato-κ2 O:O′)(quinoxaline-κN)copper(II)]
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